The size of your PWO shake should depend on your size, genetics and, to a certain extent, your goals.
50g of protein is a lot - and unless you have about 250 pounds of lean mass - it is too much. Aim for something ~0.2g x your lean mass in protein. Carbs wise, something between 0.33 to 0.5g per pound lean mass is a good target too.
In regards to timing - This looks fine to me.



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