I see nothing wrong with doing leg press into that routine. IMO Leg press finishes off the legs nicely, sometimes you have some left in your legs, but nothing left in your back thats a good place for the leg press to take over. As far as calves in the middle, well I have seen it done many times and theres nothing wrong with that either. It gives your legs a little oppurtunity to rest to give them a better chance to lift heavier weight throughout the rest of your workout. All and all it doesnt look to bad.
push and pull day are good, but leg day you have 3 quad-dominant and 2 ham dominant, I say drop both leg curls and extensions and add a compound hip dominant such as hypers, glute-hamraises, RDL, SLDL, etc.
I think it looks pretty good. My routine is very similar to that right now although I vary the weight and number of sets over a 3-week period of time. I also do a few shrugs on pull day and some tricep presses on push day.
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