A narrower grip on the bech will hit the tris a bit more.
As far as the bi's go, when you are doing pull downs you really want to work your back as much as possible. On trick that you can do, wich I do for some of my male clients that want bigger bi's, is I pre fatigue them by using a reverse grip pull down and not allowing them to extend their arms all the way up. By doing this the tension stays more concentrated on the bi's, unfortuatly this is how most people do pull downs anyway because the wieght is ussually to heavy for them to extend all the way up and then pull straight down, allowing for proper scapula-humeral rythm. So partials like that can really fry the bi's. Barbell curls are the best though, in my opinion because they keep your forearms in a completly supinated position. Also, you can try incline dumbell curls. This works well because you are placing your shoulder in extension. The long head of the bicep, the bicep brachii, is the only one of the three bicep heads wich crosses the shoulder. It performs sagital plane flexion so naturally be placing your shoulder in extenion it will strech that muscle to an optimal length. Placing this kind of stress on the muscle and performing a curl can be very effective.