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Theoretical value of cal/lbs
This is covered in any freshman chemistry book. The real question is I need to verify the validy of 9cal/gram of fat. Im sure this is an average.
The heat of combustion for lipid varies with the structural composition of the triglyceride molecule???s fatty acids. For example, 1 g of either beef or pork fat yields 9.50 kcal, whereas oxidizing 1 g of butterfat liberates 9.27 kcal. The average caloric value for 1 g of lipid in meat, fish, and eggs equals 9.50 kcal. In dairy products, the calorific equivalent amounts to 9.25 kcal per gram and in vegetables and fruits, 9.30 kcal. The average heat of combustion for lipid equals 9.4 kcal per gram.
...One can round the average net energy values to whole numbers referred to as Atwater general factors. These values, named for Wilbur Olin Atwater (1844???1907), the 19th-century chemist who pioneered human nutrition and
energy balance studies at Wesleyan College, indicate the net metabolizable
energy available to the body from ingested foods. If precise energy values for experimental or therapeutic diets are not required, the Atwater general factors provide a good estimate of the energy content of the daily diet.
ATWATER GENERAL FACTORS
??? 4 kcal per gram for dietary carbohydrate
??? 9 kcal per gram for dietary lipid
??? 4 kcal per gram for dietary protein
(source:
Sports & Exercise Nutrition, McArdle, Katch & Katch)